These recommended practices represent an overview of the methods used by cepa member companies to. The effect of the ph of ammonum nitrate solution on the. Cyclic tests of stresscorrosion cracks in steel gas pipelines with. Stress corrosion cracking scc is the growth of crack formation in a corrosive environment. The source of the co 2 is typically the decay of organic matter and geochemical reactions in the soil. The pitting occurred in the absence of chlorides at a near neutral ph where aluminum would be expected to. Marathon ashland pipe line llc mapl experienced a pipeline release on january 27, 2000 from cracking in a bottomside shallow deformation. Near neutral ph stress corrosion cracking nonclassic type a near neutral ph scc environment appears to be a dilute groundwater containing dissolved co 2. When stainless steels are fully immersed, it is rare to see chloride stress corrosion cracking at temperatures below 60 c 150 f. In air, the macro fracture shows apparent necking deformation and the. The environmental factors that increase the cracking susceptibility include higher temperatures, increased chloride content, lower ph, and higher levels of tensile stress.
Abstract nearneutralph scc has been one of the major remaining concerns to pipeline safe operation. Understanding the effects of hydrogen, hydrostatic testing. Overview of a carbon steel container corrosion model for a deep. Abstract nearneutral also termed low ph transgranular cracking of line pipe steels has been recognized as distinct from socalled highph or classical pipeline scc since the mid1980s. Influence of strain rate on the stress corrosion cracking of x70 pipeline steel in dilute near neutral ph solutions b. Chapters 3 and 5 were also submitted for publication. The crack that caused the release was determined to have propagated due to corrosion fatigue that progressed from an area of near neutral ph stress corrosion cracks.
The effect of hydrogen on the stress corrosion cracking scc for x70a and x70b pipeline steels in near neutral ph environments was studied by monotonic tensile tests on slow strain rate tests ssrt machine and cyclic tests on ssrt machine and fatigue machine. Cepa recommended practices for managing near neutral ph. Cepa recommended practices for managaing near neutral ph scc 1 of 158 3rd edition, may 2015 executive summary this 3rd stedition of the cepa recommended practices for stress corrosion cracking builds on the 1 and 2nd editions published in 1999 and 2007, respectively. It can lead to unexpected sudden failure of normally ductile metal alloys subjected to a tensile stress, especially at elevated temperature.
The buried pipelines experienced two forms of stress corrosion cracking scc, i. Experimental and theoretical approaches towards the study on mechanism of stress corrosion cracking scc of pipeline steels in near neutral ph environment have been performed. The severity of four different soil environments toward the development of near neutral ph stress corrosion cracking scc of pipeline steel was evaluated using slow strainrate testing ssrt. The earliest cracks to appear initiated at corrosion pits that formed around nonmetallic inclusions, and later cracks grew from corrosion p its that formed randomly on the surface.
This paper investigates mechanistically stress corrosion cracking scc of an x70 pipeline steel that is under cathodic protection cp in a nearneutral ph solution. In laboratory tests, nearneutral ph scc cannot in general be reproduced unless. In the case of near neutral ph scc, the undercoating water can contain dissolved carbon dioxide that. No matter how well these pipelines are designed, constructed and protected, once in place they are subjected to environmental abuse, external damage, coating disbondments, inherent mill. Influence of strain rate on the stress corrosion cracking of x70 pipeline steel in dilute nearneutral ph solutions b.
Nearneutral ph stress corrosion cracking nonclassic type a nearneutral ph scc environment appears to be a dilute groundwater containing dissolved co 2. The effect of applied potential on the stress corrosion cracking scc initiation of x70 pipeline steel in near neutral ph solution has been investigated by using a slow strain rate testing ssrt apparatus and electric potential drop epd method. High ph scc of carbon steel pipelines can occur in a highly concentrated bicarbonatecarbonate hco 3 co 3 2 solution with high ph. In the case of near neutralph scc, the cracking environment. Nearneutral ph stress corrosion cracking nonclassic type a nearneutral ph scc environment appears to be a dilute groundwater containing dissolved co2. In order to improve our understanding of its initiation mechanism a comprehensive testing setup was used in this study.
Stress corrosion cracking of pipeline steels in nearneutral ph. This paper provides an overview of mechanisms for high ph and near neutral ph stress corrosion cracking of underground pipelines. A method for predicting the location of stress corrosion cracking in a steel gas pipeline in which inline stress corrosion cracking smart tool data, external low level metal loss data and soil characterization data are compiled to predict the location of stress corrosion cracking in a steel gas pipeline segment. Weixing chen, an overview of nearneutral ph stress corrosion cracking in pipelines and mitigation strategies for its initiation and growth, corrosion. As has been proved by our previous work 77,78, x70 steel displays scc susceptibility in the nearneutral ph solution. Environmentinduced cracking of materials 1st edition. Mechanistic aspect of nearneutral ph stress corrosion. Instances of tgscc have been associated with dilute solutions with ph values in the region of 6. Stress corrosion cracking of x70 pipeline steel in near neutral ph. Nearneutral ph stress corrosion cracking of pipelines. What causes stress corrosion cracking in pipelines. Transgranular stress corrosion cracking of highpressure.
Effect of co2 on nearneutral ph stress corrosion cracking. Stress corrosion cracking of pipelines begins with a brief introduction and then explores general principals of stress corrosion cracking, including two detailed case studies of pipeline failure. The severity of four different soil environments toward the development of nearneutral ph stress corrosion cracking scc of pipeline steel was evaluated using slow strainrate testing ssrt. In the nearneutral ph solution, both dissolution of the steel and hydrogen ingress into the steel are acknowledged to be involved in the scc process of pipeline steels 38,39,40. A method for predicting the location of stress corrosion cracking in a steel gas pipeline in which in line stress corrosion cracking smart tool data, external low level metal loss data and soil characterization data are compiled to predict the location of stress corrosion cracking in a steel gas pipeline segment. The effect of applied potential on the stress corrosion cracking scc initiation of x70 pipeline steel in nearneutral ph solution has been investigated by using a slow strain rate testing ssrt apparatus and electric potential drop epd method. These recommended practices represent an overview of the methods used by cepa member companies to manage near. Although intergranular stress corrosion cracking igscc of highpressure gas pipelines has been known for more than 20 years, a transgranular form tgscc was detected more recently. The dashed line represents the test result on the same test. Ke assessment of stress corrosion cracking and hydrogen embrittlement susceptibility of buried pipeline steels a. With the superimposition of ac current 110 macm2, the direct current dc potential shifts.
Abstract nearneutralph scc has been one of the major remaining concerns. In the case of nearneutral ph scc, the undercoating water can contain dissolved carbon dioxide that. Stress corrosion cracking of pipeline steels in near neutral ph solutions. Review of stress corrosion cracking of pipeline steels in. Rogge, the role of residual stress in neutral ph stress corrosion cracking of pipeline steels. This information is then used to support proposed mechanisms for crack initiation and growth. The effect of hydrogen on the stress corrosion cracking scc for x70a and x70b pipeline steels in nearneutral ph environments was studied by monotonic tensile tests on slow strain rate tests ssrt machine and cyclic tests on ssrt machine and fatigue machine. This paper provides an overview of mechanisms for highph and nearneutral ph stress corrosion cracking of underground pipelines.
Abstract near neutral ph scc has been one of the major remaining concerns to pipeline safe operation. A mechanistic study on nearneutral ph stress corrosion cracking of pipeline steel. Cepa recommended practices for managaing nearneutral ph scc 1 of 158 3rd edition, may 2015 executive summary this 3rd stedition of the cepa recommended practices for stress corrosion cracking builds on the 1 and 2nd editions published in 1999 and 2007, respectively. Jul 17, 2017 near neutral ph stress corrosion cracking nonclassic type a near neutral ph scc environment appears to be a dilute groundwater containing dissolved co 2. An overview of nearneutral ph stress corrosion cracking. The subject of the investigations included scc susceptibility at various testing conditions, hydrogen distribution around scc crack tip and the role of hydrogen in cracking process. When cyclic loading was applied in the stress corrosion cracking initiation. Fatigue crack initiation on lowcarbon steel pipes in a. Combined effect of alternating current interference and. Environmentally induced cracking of api grade steel in near. As such, the newly discovered form of scc is equally referred to as transgranular scc or near neutral ph scc.
This research is aimed at understanding nearneutral ph scc initiation under disbonded coatings of pipeline steels, and the effect of different environmental and operational factors on crack initiation. Influence of inclusions on initiation of pitting corrosion. Lowph scc occurs in the presence of dilute ground waters containing free carbon dioxide co 2 having a. The exposure conditions involved hydrocarbon fluids following an initial hydrotest. Mechanical and environmental effects on stress corrosion cracking scc susceptibility of x52 pipeline steel were investigated using slow strain rate tests ssrt performed in a glass autoclave. A mechanistic study on nearneutral ph stress corrosion. Characteristics of nearneutralph stress corrosion cracks in an x. At the present time in china, there are plans to build.
The results showed that scc intensity increased at high cathodic protection potential. Corrosionpedia what causes stress corrosion cracking in. Investigating the mechanism of stress corrosion cracking. Effect of potential on scc initiation for pipeline steel. The source of the co2 is typically the decay of organic matter and geochemical reactions in the soil. King f 2010 stress corrosion cracking of carbon steel used fuel. Colonies of stress corrosion cracks are often seen around weld heataffected zones hazs in pipelines that are operating in the field in contact with near neutral ph nnph environment. Electrochemical noise for detection of stress corrosion. Scc crack propagation nearneutral ph solution does not occur under constant. Colonies of stress corrosion cracks are often seen around weld heataffected zones hazs in pipelines that are operating in the field in contact with nearneutral ph nnph environment. Chloride stress corrosion cracking in austenitic stainless. Corrosion susceptibility of peened friction stir welded 7075 aluminum alloy joints. Stress corrosion cracking behavior of pipeline steels in. Role of stress in transgranular stress corrosion cracking of transmission pipelines in nearneutral ph environments.
Abstract near neutral also termed low ph transgranular cracking of line pipe steels has been recognized as distinct from socalled high ph or classical pipeline scc since the mid1980s. As such, the newly discovered form of scc is equally referred to as transgranular scc or nearneutral ph scc. Near neutral ph stress corrosion crack initiaion under simulated coating disbondment. Stresscorrosion cracking of steels in ammonia with. As has been proved by our previous work 77,78, x70 steel displays scc susceptibility in the near neutral ph solution. May, 2018 near neutral ph stress corrosion cracking nonclassic type a near neutral ph scc environment appears to be a dilute groundwater containing dissolved co2. Stress corrosion cracking scc tests were conducted on american petroleum institute api grade x70 line pipe steel using smooth. This research is aimed at understanding near neutral ph scc initiation under disbonded coatings of pipeline steels, and the effect of different environmental and operational factors on crack initiation. Luo department of chemical and materials engineering, university of alberta, edmonton, alberta t6g 2g6, canada abstract the roles of dissolved hydrogen in material and anodic dissolution in the nearneutral ph stress corrosion cracking scc process of a pipeline steel was investigated. Causes of stress corrosion cracking in pipelines ducorr. Some factors affecting initiation of stress corrosion cracking of an x80 pipe steel in near neutral ph environment. Corrosion fatigue and nearneutral ph stress corrosion. No matter how well these pipelines are designed, constructed and protected, once in place they are subjected to environmental abuse, external damage, coating disbondments, inherent mill defects, soil movementsinstability and third party damage. Hydrogen in stress corrosion cracking of x70 pipeline.
It was found that there is a critical potential range, i. It has been found that low ph scc occurs in environments with a low concentration of. Influence of alternating current ac on pitting corrosion and stress corrosion cracking scc behavior of x70 pipeline steel in the nearneutral ph environment under cathodic protection cp was investigated. That is to say, scc of pipeline steels is mixcontrolled by anodic dissolution ad and hydrogen embrittlement he.
The pitting occurred in the absence of chlorides at a near neutral ph where aluminum would be expected to exhibit good resistance to corrosion. This information is then used to support proposed mechanisms for. It was found from the ssrt results that the initiation stress decreased with the decrease in the potential from 790mvsce to 950mvsce. While there is general agreement on a role for hydrogen in th. In the case of near neutral ph scc, the cracking environment. Stress corrosion cracking of pipeline steels in nearneutral ph solutions. Stress corrosion life and corrosion potential the entire stress corrosion test carried out under a constant load of 90% of the yield stress 206. Chloride stress corrosion cracking clscc is one the most common reasons why austenitic stainless steel pipework and vessels deteriorate in the chemical processing and petrochemical industries. Investigating a mechanism for transgranular stress. Nearneutral ph stress corrosion crack initiaion under simulated coating disbondment. Scc is highly chemically specific in that certain alloys are likely to undergo scc only when exposed to a small number of chemical environments. Cracking rates were studied at a range of frequencies and rvalues. Deterioration by clscc can lead to failures that have the potential to release stored energy andor hazardous substances. The mhanisms of scc m the nearneutral ph solutions were proposed based on the andysis of the results from ssrt.
Mechanistic studies on stress corrosion cracking of. Ke assessment of stress corrosion cracking and hydrogen embrittlement susceptibility of buried pipeline. The electrolyte was very dilute brine bubbled with 10% carbon dioxide. The crack that caused the release was determined to have propagated due to corrosion fatigue that progressed from an area of nearneutral ph stress corrosion cracks. Experimental and theoretical approaches towards the study on mechanism of stress corrosion cracking scc of pipeline steels in nearneutral ph environment have been performed. Some factors affecting initiation of stress corrosion. Proceedings of the 2018 12th international pipeline conference.
Scc in pipelines is a type of environmentally assisted cracking eac. The localized pitting corrosion was produced in aluminum floats on a storage tank roof. Lowph scc or near neutral ph on the outer surface of pipelines is associated with specific soil conditions at free corrosion potential, where cathodic protection is ineffective. Environmentally induced cracking of api grade steel in. Fatigue crack growth modelling for pipeline carbon steels under gaseous. The relationship between inclusions and stress corrosion cracking is investigated by ssrt test and sem observation of the side surface morphologies. Different electrochemical techniques have been used to estimate the risk of the scc. Characteristics of nearneutralph stress corrosion cracks. A mechanistic study on nearneutral ph stress corrosion cracking of pipeline steel b. Role of stress in transgranular stress corrosion cracking. Mechanisms of highph and nearneutralph scc of underground. Research on stress corrosion cracking scc of welded line pipe steel can contribute knowledge that is important in establishing pipeline integrity. Some factors affecting initiation of stress corrosion cracking of an x80 pipe steel in nearneutral ph environment. Characteristics and historical information on both forms of cracking are discussed.
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